Skip to main content
U.S. flag

An official website of the United States government

Dot Gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

HTTPS

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Major Regional-scale Production of O3 and Secondary Organic Aerosol In Remote Amazon Regions From The Dynamics and Photochemistry of Urban and Forest Emissions

Abstract

The Amazon rainforest suffers increasing pressure from anthropogenic activities. A key aspect not fully understood is how anthropogenic atmospheric emissions within the basin interact with biogenic emissions and impact the forest’s atmosphere and biosphere. We combine a high-resolution atmospheric chemical transport model with an improved emissions inventory and in-situ measurements to investigate a surprisingly high concentration of ozone (O3) and secondary organic aerosol (SOA) 150–200 km downwind of Manaus city in an otherwise pristine forested region. We show that atmospheric dynamics and photochemistry determine a gross production of secondary pollutants seen in the simulation. After sunrise, the erosion of the nocturnal boundary layer mixes natural forest emissions, rich in biogenic volatile organic compounds, with a lofted pollution layer transported overnight, rich in nitrogen oxides and formaldehyde. As a result, O3 and SOA concentrations greater than ∼47 ppbv and 1.8 μg m–3, respectively, were found, with maximum concentrations occurring at 2 pm LT, 150–200 km downwind of Manaus city. These high concentrations affect a large primary forested area of about 11,250 km2. These oxidative areas are under a NOx-limited regime so that changes in NOx emissions from Manaus have a significant impact on O3 and SOA production.

Article / Publication Data
Active/Online
YES
Available Metadata
DOI ↗
Early Online Release
July 08, 2022
Fiscal Year
Peer Reviewed
YES
Publication Name
Environmental Science & Technology
Published On
July 19, 2022
Publisher Name
American Chemical Society
Print Volume
56
Issue
14
URL ↗

Institutions

Not available

Author

Authors who have authored or contributed to this publication.